Dalton Transactions, Volume 47, Issue 21, Pages 7118-7122 , 01/01/2018

Self-assembly of a mixed-valence FeII-FeIII tetranuclear star

Darunee Sertphon, Phimphaka Harding, Keith S. Murray, Boujemaa Moubaraki, Nicholas F. Chilton, Stephen Hill, Jonathan Marbey, Harry Adams, Casey G. Davies, Guy N.L. Jameson, David J. Harding

Abstract

A unique self-assembled mixed-valence Fe<sup>II</sup>-Fe<sup>III</sup> tetranuclear star has been comprehensively characterised showing a large magnetic anisotropy at the peripheral Fe<sup>II</sup> centres, ferromagnetic coupling between the iron centres and field-induced SMM behaviour.

Document Type

Article

Source Type

Journal

ASJC Subject Area

Chemistry : Inorganic Chemistry

Funding Agency

National Science Foundation


Bibliography


Sertphon, D., Harding, P., Murray, K., Moubaraki, B., Chilton, N., Hill, S., Marbey, J., ... Harding, D. (2018). Self-assembly of a mixed-valence FeII-FeIII tetranuclear star. Dalton Transactions, 47(21) 7118-7122. doi:10.1039/c8dt01241e

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