Ceramics International, Volume 39, Issue 5, Pages 5597-5608 , 01/07/2013

Optical, photocatalytic and bactericidal properties of Zn 1-xLaxO and Zn1-xMgxO nanostructures prepared by a sol-gel method

Sumetha Suwanboon, Pongsaton Amornpitoksuk, Phuwadol Bangrak, Nantakan Muensit

Abstract

Multifunctional Zn<inf>1-x</inf>La<inf>x</inf>O and Zn<inf>1-x</inf>Mg <inf>x</inf>O nanostructures were successfully synthesized through a sol-gel method. Thecrystal structure, morphology, specific surface area and thermal behavior were investigated by X-ray diffractometer (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) and a thermogravimetric and differential thermal analyzer (TG-DTA), respectively. The optical properties were determined with a UV-vis spectrophotometer and a photoluminescent spectrometer. The crystallite size decreased when the La and Mg concentrations increased to x=0.05. The Zn <inf>0.9</inf>Mg<inf>0.1</inf>O nanostructure showed the widest E<inf>g</inf> value of 3.30 eV. The Zn<inf>0.95</inf> Mg<inf>0.05</inf>O nanostructure exhibited the highest efficiency for the photocatalytic degradation of methylene blue (MB)with a rate constant (k) of 0.0440 min<sup>-1</sup>. Both La- and Mg-doped ZnO nanostructures inhibited Staphylococcus aureus (S. aureus) and to a less extent Escherichia coli (E. coli). © 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

Document Type

Article

Source Type

Journal

ASJC Subject Area

Materials Science : Electronic, Optical and Magnetic MaterialsMaterials Science : Surfaces, Coatings and FilmsChemical Engineering : Process Chemistry and TechnologyMaterials Science : Materials ChemistryMaterials Science : Ceramics and Composites

Funding Agency

Prince of Songkla University


Bibliography


Suwanboon, S., Amornpitoksuk, P., Bangrak, P., & Muensit, N. (2013). Optical, photocatalytic and bactericidal properties of Zn 1-xLaxO and Zn1-xMgxO nanostructures prepared by a sol-gel method. Ceramics International, 39(5) 5597-5608. doi:10.1016/j.ceramint.2012.12.075

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