Chemical Communications, Volume 49, Issue 56, Pages 6340-6342 , 18/06/2013

Abrupt spin crossover in an iron(iii) quinolylsalicylaldimine complex: Structural insights and solvent effects

David J. Harding, Wasinee Phonsri, Phimphaka Harding, Ian A. Gass, Keith S. Murray, Boujemaa Moubaraki, John D. Cashion, Lujia Liud, Shane G. Telfer

Abstract

The first Fe(<sup>iii</sup>) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)<inf>2</inf>]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described. © 2013 The Royal Society of Chemistry.

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Article

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Journal

ASJC Subject Area

Chemistry : Chemistry (all)Materials Science : Metals and AlloysMaterials Science : Electronic, Optical and Magnetic MaterialsMaterials Science : Materials ChemistryChemical Engineering : CatalysisMaterials Science : Ceramics and CompositesMaterials Science : Surfaces, Coatings and Films

Access to Document

DOI : 10.1039/c3cc42125b
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Bibliography


Harding, D., Phonsri, W., Harding, P., Gass, I., Murray, K., Moubaraki, B., Cashion, J., ... Telfer, S. (2013). Abrupt spin crossover in an iron(iii) quinolylsalicylaldimine complex: Structural insights and solvent effects. Chemical Communications, 49(56) 6340-6342. doi:10.1039/c3cc42125b

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