Acta Crystallographica Section E Structure Reports Online, Volume 68, Issue 8, Pages m1026 , 01/08/2012
Trans-Bis(nitrato-O)bis-(1,10-phenanthroline-k2N,N′) manganese(II)
Abstract
In the title compound, [Mn(NO<inf>3</inf>)<inf>2</inf>(C<inf>12</inf>H <inf>8</inf>N<inf>2</inf>)<inf>2</inf>], the Mn<sup>II</sup> atom lies on a twofold rotation axis, and is six-coordinated in a distorted trans-N <inf>4</inf>O<inf>2</inf> octa-hedral environment by four N atoms from two 1,10-phenanthroline ligands and two O atoms from two nitrate anions. The nitrate anion is disordered about a twofold rotation axis with fixed occupancy factors of 0.5. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 4.088 (5) Å] into a three-dimensional supra-molecular network.
Document Type
Article
Source Type
Journal
Keywords
data-to-parameter ratio = 13.5disorder in main residuemean σ(C-C) = 0.003 ÅR factor = 0.045single-crystal X-ray studyT = 298 KwR factor = 0.101
ASJC Subject Area
Chemistry : Chemistry (all)Materials Science : Materials Science (all)Physics and Astronomy : Condensed Matter Physics