Acta Crystallographica Section E Structure Reports Online, Volume 67, Issue 4, Pages m477-m478 , 01/04/2011
(Di-2-pyridylamine-K-2N,N′)[hydrotris-(3,5- diphenylpyrazol-1-yl-KN 2)borato]nickel(II) bromide dichloromethane monosolvate
Abstract
In the title compound, [Ni(C<inf>45</inf>H<inf>34</inf>BN <inf>6</inf>)(C<inf>10</inf>H<inf>9</inf>N<inf>3</inf>)]Br·CH <inf>2</inf>Cl<inf>2</inf>, the Ni<sup>II</sup> atom is five-coordinated by the tridentate hydrotris-(3,5-diphenylpyrazolyl)borate ligand and a bidentate di-2-pyridyl-amine ligand in a distorted square-pyramidal geometry. In the crystal, intermolecular N - H⋯Br and C - H⋯Br hydrogen bonds link the Ni complex cations and the Br<sup>-</sup> ions, forming a chain along the c axis.
Document Type
Article
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Journal
ASJC Subject Area
Chemistry : Chemistry (all)Materials Science : Materials Science (all)Physics and Astronomy : Condensed Matter Physics