Acta Crystallographica Section E Structure Reports Online, Volume 67, Issue 4, Pages m404-m405 , 01/04/2011

[4-Bromo-N-(pyridin-2-ylmethylidene)-aniline-k2N,N′]bis(1, 1,1,5,5,5-hexafluoropentane-2,4-dionato-k2O,O′)-nickel(II)

Phimphaka Harding, David J. Harding, Nitisastr Soponrat, Harry Adams

Abstract

The title compound, [Ni(C<inf>5</inf>HF<inf>6</inf>O<inf>2</inf>)2(C <inf>12</inf>H<inf>9</inf>BrN<inf>2</inf>)], the Ni<sup>II</sup> atom exhibits a pseudo-octa-hedral coordination geometry. The structure packs throuh C - H⋯Br interactions, forming a hydrogen-bonded ladder. There are also strong hydrogen-bonding interactions between two of the O atoms of the Β-diketonate ligands and two H atoms on the pyridine ring of the Schiff base ligand.

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Article

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Journal

ASJC Subject Area

Chemistry : Chemistry (all)Materials Science : Materials Science (all)Physics and Astronomy : Condensed Matter Physics

Access to Document

DOI : 10.1107/S1600536811005599
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Bibliography


Harding, P., Harding, D., Soponrat, N., & Adams, H. (2011). [4-Bromo-N-(pyridin-2-ylmethylidene)-aniline-k2N,N′]bis(1, 1,1,5,5,5-hexafluoropentane-2,4-dionato-k2O,O′)-nickel(II). Acta Crystallographica Section E Structure Reports Online, 67(4) m404-m405. doi:10.1107/S1600536811005599

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