Acta Crystallographica Section E Structure Reports Online, Volume 65, Issue 7, Pages m773 , 27/07/2009
[Tris(3,5-diphenylpyrazolyl)hydroborato]nickel(II) bromide
Abstract
In the title tris-(pyrazol-yl)borate (Tp<sup>Ph2</sup>) complex, [NiBr(C<inf>45</inf>H<inf>34</inf>BN<inf>6</inf>)], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN3Br tetra-hedral geometry arises for the metal ion. In the crystal, C - H⋯(C=C) and C - H⋯π inter-actions help to establish the polar crystal packing.
Document Type
Article
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Journal
ASJC Subject Area
Chemistry : Chemistry (all)Materials Science : Materials Science (all)Physics and Astronomy : Condensed Matter Physics