Inorganica Chimica Acta, Volume 362, Issue 7, Pages 2435-2439 , 15/05/2009
Microwave synthesis, spectroscopy, thermal analysis and crystal structure of an one-dimensional polymeric {[Cu(4,4′-bipy)(H2O)3(SO4)] · 2H2O}n complex
Abstract
A metal organic-inorganic coordination framework formulated as {[Cu(4,4′-bipy)(H<inf>2</inf>O)<inf>3</inf>(SO<inf>4</inf>)] · 2H<inf>2</inf>O}<inf>n</inf> (1) (where 4,4′-bipy = 4,4′-bipyridine) has been successfully prepared by microwave synthesis. The title complex has been characterized by single crystal X-ray crystallography, FT-IR spectroscopy and thermal analysis. Complex (1) is an one-dimensional (1D) polymer in which 4,4′-bipy acts as a bridging ligand supporting the formation of infinite [Cu(4,4′-bipy)(H<inf>2</inf>O)<inf>3</inf>(SO<inf>4</inf>)] chains. The packing diagram shows that a 3D network is formed via hydrogen bonds. The infrared spectra and thermographic data are consistent with the chemical formula. © 2008 Elsevier B.V. All rights reserved.
Document Type
Article
Source Type
Journal
Keywords
4,4′-BipyridineCopper complexMicrowave synthesisOne-dimensional polymeric complexOrganic-inorganic coordination framework
ASJC Subject Area
Chemistry : Inorganic ChemistryChemistry : Physical and Theoretical ChemistryMaterials Science : Materials Chemistry
Phetmung, H., Wongsawat, S., Pakawatchai, C., & Harding, D. (2009). Microwave synthesis, spectroscopy, thermal analysis and crystal structure of an one-dimensional polymeric {[Cu(4,4′-bipy)(H2O)3(SO4)] · 2H2O}n complex. Inorganica Chimica Acta, 362(7) 2435-2439. doi:10.1016/j.ica.2008.10.038