Acta Crystallographica Section E Structure Reports Online, Volume 64, Issue 12, Pages m1538 , 12/12/2008
Tris(phenanthroline-κ2 N,N′)cobalt(II) tetra-fluoridoborate acetonitrile solvate
Abstract
In the crystal structure of the title compound, [Co(C12H8N2)3](BF4) 2·CH3CN, the mol-ecular packing involves dimers of distorted octahedrally coordinated cations which are held together by one π-π [centroid-centroid = 3.542 (4) Å] and two C - H⋯π inter-actions [2.573 (4) Å] resulting in a P4AE (Parallel Fourfold Aryl Embrace) motif. The anions are found in aryl boxes formed from the phenanthroline ligands. © 2008.
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Article
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Journal
ASJC Subject Area
Chemistry : Chemistry (all)Materials Science : Materials Science (all)Physics and Astronomy : Condensed Matter Physics