Acta Crystallographica Section E Structure Reports Online, Volume 62, Issue 6, Pages m1335-m1337 , 01/06/2006

Catena-Poly[[bis[μ-1-(2-pyridyl)pyridinium-2-thiolate] -κ2N:S;κ2S:N-dicopper(I)]-di-μ-chloro]

Phimphaka Harding, David J. Harding, Chaveng Pakawatchai, Hirihattaya Phetmung

Abstract

The reaction of copper(II) chloride with pyridine-2-thiol affords the title complex, [Cu<inf>2</inf>Cl<inf>2</inf>(C<inf>10</inf>H<inf>8</inf>N <inf>2</inf>S)<inf>2</inf>]<inf>n</inf>, in which two pyridine-2-thiol molecules have reacted to give a betain ligand and the copper centre has undergone reduction. The copper metal centre exhibits a distorted tetrahedral coordination geometry with bridging chloride and 1-(2-pyridyl)pyridinium-2-thiolate ligands, giving centrosymmetric dimers further linked into a polymeric chain. © 2006 International Union of Crystallography. All rights reserved.

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Article

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Journal

ASJC Subject Area

Chemistry : Chemistry (all)Materials Science : Materials Science (all)Physics and Astronomy : Condensed Matter Physics

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DOI : 10.1107/S1600536806017028
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Harding, P., Harding, D., Pakawatchai, C., & Phetmung, H. (2006). Catena-Poly[[bis[μ-1-(2-pyridyl)pyridinium-2-thiolate] -κ2N:S;κ2S:N-dicopper(I)]-di-μ-chloro]. Acta Crystallographica Section E Structure Reports Online, 62(6) m1335-m1337. doi:10.1107/S1600536806017028

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